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T. W. Swaddle. Academic: San Diego, 1997. xvi +
429 pp + appendices and index. 16.0 x 23.5 cm. ISBN
0-12-678550-3. $65.00.
Inorganic chemistry draws its strength from its
great practical utility, and this book represents the subject
from the standpoint of applications rather than the
customary views of symmetry point groups, quantum mechanics,
and numerous bonding theories. This is not your
traditional Junior/Senior/1st-year-graduate-student inorganic text.
The book's central purposes are to explain the role
of inorganic chemistry in the modern world and to provide
a source book of readable proportions for students,
scientists, engineers, and the interested public. The text is a
cornucopia of descriptive chemistry combined with an
appropriate blend of theory and experiment to explain and support
its central topics.
The text is organized as 19 chapters, 6 appendices,
and an index. The chapter titles are:
- Importance of Inorganic Chemistry, 10 pp
- Chemical Energetics, 39 pp
- Catenation: Inorganic Macromolecules, 17 pp
- Crystalline Solids, 25 pp
- The Defect Solid State 19 pp
- Inorganic Solids as Heterogeneous Catalysts, 13 pp
- Silicates, Aluminates, and Phosphates, 23 pp
- The Atmosphere and Atmospheric Pollution, 25 pp
- Nitrogen, Phosphorus, and Potash in Agriculture, 11 pp
- Sulfur and Sulfur Compounds, 15 pp
- Alkalis and Related Products, 15 pp
- The Halogens, 15 pp
- Ions in Solution, 25 pp
- Water Conditioning, 21 pp
- Oxidation and Reduction in Solution, 41 pp
- Corrosion of Metals, 29 pp
- Extractive Metallurgy, 33 pp
- Organometallics, 19 pp
- Some Newer Solid-State Technologies, 19 pp
Chapter titles alone do not tell the whole story
because they hide a diverse yet interesting collection of
subtopics. Most chapters are shortideal to hold the interest of
undergraduate students yet packed with information and,
yes, some chemistry. For example, Chapter 8, on the
atmosphere and atmospheric pollution, contains individual
subsections titled Carbon dioxide and the Greenhouse Effect;
Other greenhouse gases; Supercritical carbon dioxide;
Carbon monoxide; Ozone; The stratospheric ozone layer; Ozone
as a pollutant; Nitrous oxide; Nitric oxide and nitrogen
dioxide; and Sulfur dioxide and trioxide. Each chapter ends
with a half-dozen or so application exercises for students
(answers to some problems are given, but most do not
have printed answers).
Oxidationreduction processes play an
important chemical role in most everyday applications and we
find here that redox is the common thread that connects all
the chapters. Interested in discovering what Pourbaix
diagrams and overpotential are all about? Chapter 15 spells it
out along with the nature of fuel cells, electrochemical
storage cells, electrolysis, electroplating, and electroforming.
Not satisfied and need more for your money? Look
at the subtopics in Chapter 16: Bimetallic corrosion;
Corrosion by oxygen; Bimetallic corrosion of iron; Single-metal corrosion; Role of oxide films; Crevice and
intergranular corrosion; Corrosion by acids and with complexing
agents; The role of overpotential in corrosion; Cathodic
protection; Protective coatings; Corrosion inhibitors; Atmospheric
corrosion; and finally, Corrosion-resistant metals.
A reader seeking information on one particular
topic can easily find supporting information. Sources of
additional information are given at the end of each
chapter; most are monographs or reviews that contain citations
to the primary literature. References are often made to
the original sources or to authoritative scientific news articles.
Inorganic Chemistry: An Industrial and
Environmental Perspective is intended to provide its readership with
a concise overview of the applications of inorganic
chemistry in a world that is increasingly dominated by technology
and its ramifications. It should find a niche either as a
textbook for an independent one-semester course in applied
inorganic chemistry or as a complement to a
conventional academic text in a full-year course on inorganic
chemistry. Professor Swaddle's graceful writing style will be
appreciated by students, who, after reading a paragraph or
two, will be able to say: "Hey, that makes sense", rather
than "What does this say?" It will find favor with educators,
practicing engineers, geologists, environmental scientists,
and entrepreneurs as a compact reference book and guide to
the title subject.
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