|
The best way to obtain a copy of this book is from the author: Ken Leffek,
980 Kentwood Terrace, Victoria, BC, Canada, V 8Y 1A6. Telephone and fax:
250/658-1329.
In recent years, many more biographies of
chemists seem to have been published than ever before. One
reason, of course, may be that there are many more chemists
and, in fact, it is possible that there are actually fewer
biographies published per capita in the chemical world. The
character of those I have read in recent years is quite
variable. For example, recent biographies of Linus Pauling are
somewhat derivative, in the "gotcha" style of modern
journalism; in contrast, the books in the ACS autobiographical
Profiles series are, for the most part, rather specialized reviews
of the individual's chemical contributions, usually made
more generally interesting by numerous photographs of the
individual, his family, and colleagues.
The Leffek biography of Sir Christopher Ingold is
quite different. While clearly written with reverence for its
subject, it is a remarkably thorough account of the life of a
very important figure in what I prefer to call
"organophysical" chemistry. What I mean by this term is the application
of physical methods to organic chemistry, as opposed to
"physical organic", which I take to be the application of
synthetic methodology to prepare compounds with structures
designed to test critical concepts of physical theory.
What Ingold brought to the table, most particularly, was the
use of reaction kinetics to study the mechanisms of
nitration, displacement, and elimination reactions, and of
sophisticated spectroscopy to define the ground and first
excited states of benzene. The mechanistic work is well known
and has become a large part of basic organic
chemistryso much so that it is possible and ironic that in not many
more years, Hughes and Ingold might not be identified by
name in elementary organic texts in juxtaposition with their
contributions, even though the names of Hoffmann
and Saytzeff are likely to persist.
An extraordinary difficulty for the Ingold
biographer was that there was no treasure trove of Ingold papers
available to analyze. I remember some years ago receiving a
letter from Professor Leffek asking if I had anything
useful for him in my own files (unfortunately very little,
although I remember Ingold well). Despite this, the author
persisted and there is more than ample detail on the whole of
Ingold's life without the sort of "docufication" that, in my
view, marred some of the Pauling biographies. The accounts
of how the University College Chemistry Department
operated in Ingold's time are detailed and very interesting.
Many book reviews are popular because they give
you so much information that you can talk about the book
intelligently without ever having to read it, but I am not
going to do that for you here. If you are interested in
organic chemistry, this is a wonderful book to read because it
places Ingold and his work in a rich historical context of the
English and continental chemistry of his time. However,
the context is a bit parochial in that it pretty much stops
at ocean's edge. The index has one reference each to
S. Winstein and L. P. Hammett, but none to J. B. Conant
and P. D. Bartlettwho, I think, did as much for reaction
mechanism studies in organic chemistry as Ingold. One who
has read Derek Davenport's wonderful essay
(Chemtech 1987, 526) on the "invective effect" in organic chemistry will
no doubt be surprised to find H. C. Brown absent from the
index as well.
So, I suggest you get Leffek's book and find the
answers to questions such as: What was Ingold doing on the Isle
of Wight? Why did Ingold mix 39.2 gallons of ethyl alcohol
into a ton of ethyl iodoacetate? What was Ingold doing at
Cassel Cyanide and how can you save yourself when your
clothes are dampened with a spill of liquid HCN? What was
the ThorpeIngold valence-deflection hypothesis? How did
being gassed with phosgene influence Ingold's marriage?
Who won in the monumental battle of often harsh words
between Sir Robert Robinson and cohorts versus C. K. Ingold
and his supporters that produced some 45 rather juicy
communications in three years? What was Ingold doing at
Leeds? How did the fruitful 33-year collaboration with E.
D. Hughes come about, and what was Hughes like as a
person? How did Ingold determine the symmetrical
structure of benzene? What did Ingold do during World War II?
Why did Ingold never receive a Nobel Prize? How was Ingold
connected to the razor-blade wars between the Gillette
and Wilkinson companies? All of the above and more can
be learned by reading Leffek's book. I highly recommend it!
|