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  Home > JCE Print > Journal of Chemical Education > Issues > 1997  > October  >
Chemical Education Today
Letters
Group Theory in Advanced Inorganic Chemistry
Brahama D. Sharma
P.O. Box 1626, Pismo Beach, CA 93448-1626

Cover
October 1997
Vol. 74 No. 10
p. 1152

Full Text
Faltynek (J. Chem. Educ. 1995, 72, 20-24) discusses some very important points. We wish to draw attention to the work by Sharma (J. Chem. Educ. 1982, 59, 554-557), which addressed the problems cited by Faltynek. It is unfortunate that the most recent work might introduce the wrong impressions that were hopefully eradicated by Sharma in 1982, and is constrained to orthogonal axes.

We quote from the 1995 work (p 20, paragraph 2, line 13): "An improper rotation is a binary operation involving consecutive application of the unitary operations of rotation and reflection through a perpendicular plane (Cnmsh = shCnm = Snm)." This does not take into account explicitly that the operation does not mean that a symmetry element exists. We quote from the 1982 work, to make this clear (p 554, under the heading Schöenflies Notation): "In the Schöenflies notation, at the very outset, one needs to reckon with two different ways of writing the symbols, namely the boldface (or italic symbols) and the ordinary symbols. These symbols employing the same letter and number mean two entirely different ideas." Further on page 555 under the subheading Spectroscopist's Alternating (Rotatory-Reflection) Axes, we have "Point groups possessing just alternating axes, symbolized as Sn, involve an n-fold counterclockwise rotation of a motif to give an imaginary motif." The word imaginary is crucial in that students should never get any lingering thought that a rotation axis or a mirror plane exists.

Finally, most discussions on symmetry are based upon just the spectroscopist's viewpoint. No attention is paid the well known Hermann–Mauguin concepts of the crystallographic point of view. I was fortunate in that I had exposure to both view points. I urge the readers to study the excellent article by the late J. D. H. Donnay (Acta Crystallogr. 1972, A28, S110 and the references cited therein.).

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Sharma, Brahama D. J. Chem. Educ. 1997 74 1152.
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Last Updated:
July 27, 1999
June 23, 2005
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