A first-order reversible reaction is simulated on an overhead projector using small coins or discs.
A simulation is carried out in which initially there are 24 discs representing reactant A and none
representing reactant B. At the end of each minute half of the reactant A discs get converted to
reactant B, and one quarter of the reactant B discs get converted to reactant A discs. Equilibrium
is established with 8 A discs and 16 B discs, and no further net change is observed as the simulation
continues. Another simulation beginning with 48 A discs and 0 B discs leads at equilibrium to 16 A
discs and 32 B discs. These results illustrate how dynamic equilibria are established and allow the
introduction of the concept of an equilibrium constant. Le Châtelier's principle is illustrated by
further simulations.
More Information
Citation
Harrison, John A.; Buckley, Paul D. J. Chem. Educ.2000 77 1013.
Keywords
General Chemistry; Equilibrium; Demonstrations; Teaching/Learning Aids
The "Chemistry Teacher Connection" (CTC) is especially for high school chemistry teachers. For only $40/year, it offers an online-only subscription to CLIC along with membership in the Division of Chemical Education, normally $65/year. CTC subscribers receive access to all articles and supplements from 1996 through the current issue.
Through special arrangement with the ACS, JCE High School CLIC is now able to provide subscribers with online access to Chemical & Engineering News articles that have been selected specifically for secondary science instructors and their students.
Occasionally, collections of JCE back issues become available for donation to individual teachers, schools, or libraries. JCE matches collections with interested recipients. Recipients pay shipping costs or pick up the collection.