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  Home > JCE Print > Journal of Chemical Education > Issues > 2000  > November  >
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Electrical Deflection of Polar Liquid Streams: A Misunderstood Demonstration
Maryam Ziaei-Moayyed and Edward Goodman
Honors College, Arizona State University, Tempe, AZ 85287-1604

Peter Williams
Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604

Cover
November 2000
Vol. 77 No. 11
p. 1520

Abstract
The electrical deflection of polar liquid streams, commonly used as a textbook illustration of the behavior of polar molecules, is shown to be due to the formation of electrically charged droplets in the polar liquid stream, induced by a nearby charged object, rather than any force exerted on molecular dipoles. Streams of water and polar organic liquids could be deflected in a uniform electric field, which could not have exerted any force on dipolar species. Water and polar organic liquid streams formed within a grounded, electrically screened region could not be deflected after exiting the screened region, demonstrating that there is no electrical force on uncharged polar liquid droplets. Induced charging was observed also in insulating polar organic liquids and is suggested to be due to ionic impurities. A weak deflection of a stream of a nonpolar liquid (tetrachloroethylene) was also observed, indicating that such impurity effects are quite general, even in nonpolar liquids.
More Information
*  Citation
Ziaei-Moayyed, Maryam; Goodman, Edward; Williams, Peter. J. Chem. Educ. 2000 77 1520.
*  Keywords
Demonstrations; General Chemistry; Textbooks
*  History
Created:
Last Updated:
October 6, 2000
April 15, 2005
  Home > JCE Print > Journal of Chemical Education > Issues > 2000 > November > Page 1520



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