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  Home > JCE Print > Journal of Chemical Education > Issues > 2003  > July  >
Chemical Education Today
Letters
Improved Hittorf Apparatus
Kan Jinquing
Department of Chemistry, Yangzhou University School of Sciences, Yangzhou 225002, P. R. China

Cover
July 2003
Vol. 80 No. 7
p. 742

Full Text

The authors reply to Bader

We thank Morris Bader for his interest in our manuscript. While some statements in the article may have been ambiguous, we hope readers will consider these facts.

  1. Please remember that the concentration value for HCl and NaOH solutions found in Table 1 is much less than 0.1 mol dm-3.
  2. We did not reject “the basic premise of the Hittorf method” in our article. On the contrary, we stated that “It yields an apparent transference number, which cannot be distinguished from the results obtained by the moving-boundary method” (1). Strictly, the concentration unit in electrochemistry should be mol kg-1 (i.e., molal), but in diluted solutions there is no difference between molarity (i.e., mol dm-3) and molal, so molal can be displaced by molarity in diluted solution.
  3. The electrode used in our experiment is inactive (a graphite or Pt electrode); we obtained the RSD values after running the experiment eight times.

We also refer interested readers to the relevant sections of the texts listed below (2, 3).

Literature Cited

  1. Jinqing, K.; Qin, X.; Ke, C. J. Chem. Educ. 2001, 78, 937–938.
  2. Moelwyn-Hughes, E. A. Physical Chemistry; Pergamon Press: London, 1957; pp 838–839.
  3. Erkang, Sun, et al. Experimental of Physical Chemistry; Nanjin University Press: Nanjin, 1998; pp 72–75.
More Information
*  Citation
Jinquing, Kan. J. Chem. Educ. 2003 80 742.
*  Keywords
Electrochemistry; Laboratory Equipment / Apparatus; Physical Chemistry
*  History
Created:
Last Updated:
June 4, 2003
February 28, 2005
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