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  Home > JCE Print > Journal of Chemical Education > Issues > 2004  > December  >
In the Laboratory
Copper Metal from Malachite circa 4000 B.C.E.
Gordon T. Yee and Jeannine E. Eddleton
Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061

Cris E. Johnson
Department of Chemistry, University of Colorado at Colorado Springs, Colorado Springs, CO 80933

Cover
December 2004
Vol. 81 No. 12
p. 1777

Abstract
After the development of the field of ceramics, for Stone Age man, the smelting of copper might have represented the next designed chemical transformation of one substance into a more useful second substance. Around 6000 years ago the procedure involved heating copper ore in the presence of charcoal; we have created a laboratory experiment inspired by this idea. The experiment starts with a naturally occurring ore, malachite, essentially pure Cu2CO3(OH)2, which is readily available at modest cost in bead form from jewelry stores. Using only a Bunsen burner, a porcelain crucible, and a charcoal briquette, the experiment demonstrates two steps in the ancient processing of copper ore: roasting and reduction. The product is a shiny copper metal bead that can then be hammered, polished, and shown to be electrically conductive. The procedure requires less than three hours, uses inexpensive materials and equipment, uses no hazardous reagents, and produces essentially no hazardous waste. In addition, the student has produced something tangible, that can either be the subject of further experimentation, or safely taken home.

Featured on the Cover

Supplement
Instructions for the students, data worksheet, and notes for the instructor, including answers to the pre- and postlab questions, are available.
*  Contents JCE2004p1777W.doc (Microsoft Word)
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More Information
*  Citation
Yee, Gordon T.; Eddleton, Jeannine E.; Johnson, Cris E. J. Chem. Educ. 2004 81 1777.
*  Keywords
Copper; General Chemistry; History / Philosophy; Inorganic Chemistry; Inquiry-Based / Discovery Method; Introductory / High School Chemistry; Laboratory Instruction; Metals; Redox Reactions; Solids
*  History
Created:
Last Updated:
November 1, 2004
November 9, 2004
  Home > JCE Print > Journal of Chemical Education > Issues > 2004  > December  > Page 1777



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