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  Home > JCE Print > Journal of Chemical Education > Issues > 2006  > September  >
Chemical Education Today
Letters
More on the Nature of Resonance
Robert C. Kerber
Chemistry Department, State University of New York at Stony Brook, Long Island, NY 11794-3400
Cover
September 2006
Vol. 83 No. 9
p. 1291

Full Text

The author replies to Jensen.

I thank Prof. Jensen for his interesting and informative expansion on some of the history underlying the resonance concept. I particularly like his characterization of the use of contributing structures as “an artifact of an impoverished chemical symbolism”. Nevertheless, I continue to find the use of delocalization preferable to resonance. The former is misleading only if taken in an absolute sense, as implying that electrons in methane (for example) are totally locked in place and those in benzene are totally free. Understanding delocalization as a relative term reduces the potential for misunderstanding, in my opinion. And, empirically, generations of students have been confused by the resonance terminology. If Pauling was confused, how can we expect our students not to be confused? Perhaps we need a clean new term, or perhaps mesomerism should rise again?

More Information
*  Citation
Kerber, Robert C. . J. Chem. Educ. 2006 83 1291.
*  Keywords
Aromatic Compounds; Covalent Bonding; First-Year Undergraduate / General; History / Philosophy; Misconceptions / Discrepant Events; Molecular Properties / Structure; Nomenclature / Units / Symbols; Organic Chemistry; Resonance Theory; Textbooks / Reference Books
*  History
Created:
Last Updated:
8/7/2006
8/14/2006
  Home > JCE Print > Journal of Chemical Education > Issues > 2006  > September > Page 1291



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