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  Home > JCE Print > Journal of Chemical Education > Issues > 2009  > November  >
survey
In the Classroom
JCE DigiDemos: Tested Demonstrations
The Remarkable Chemistry of Potassium Dioxide(1–)
Two Microscale Classroom Demonstrations
Andrew Allen, Michael Anderson, and Bruce Mattson
Department of Chemistry, Creighton University, Omaha, NE 68178

checked by Kenneth S. Lyle
Department of Chemistry, Duke University, Durham, NC 27708

Cover
November 2009
Vol. 86 No. 11
p. 1286

Abstract
Potassium dioxide, KO2, (potassium superoxide) is an important compound owing to its ability to react with carbon dioxide to produce oxygen. This unique ability is employed to design rebreathing devices for submarines, space vehicles, and space suits. "Rebreathers" for firefighters and miners have also been designed using potassium superoxide. We provide instructions for performing two classroom demonstrations: (a) The demonstration of potassium superoxide's ability to react nearly quantitatively with carbon dioxide, and (b) the paramagnetism of potassium superoxide. Five confirmatory experiments are described in support of the first demonstration.
More Information
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Citation
Allen, Andrew; Anderson, Michael; Mattson, Bruce. J. Chem. Educ. 2009, 86, 1286.
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Keywords
Demonstrations; Descriptive Chemistry; First-Year Undergraduate / General; Free Radicals; Gases; Hands-On Learning / Manipulatives; High School / Introductory Chemistry; Inorganic Chemistry; Inquiry-Based / Discovery Learning; Magnetic Properties; Main-Group Elements; Molecular Properties / Structure; Nonmetals; Oxygen; Reactions; Upper-Division Undergraduate
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History
Created:
Last Updated:
9/16/2009
9/25/2009
 Caution! 
Experiments, laboratory exercises, lecture demonstrations, and other descriptions of the use of chemicals, apparatus, instruments, computers, and computer interfaces are presented in the Journal of Chemical Education as illustrative of new or improved ideas or concepts in chemistry instruction and are directed at qualified teachers. Although every effort is made to assure and encourage safe practices and safe use of chemicals, the Journal of Chemical Education cannot assume responsibility for uses made of its published materials. Many chemicals are hazardous. Precautions for the safe use of hazardous chemicals and directions for their proper disposal are described in the Material Safety Data Sheets and on the labels. We strongly urge all those planning to use materials from our pages to make choices and to develop procedures for laboratory and classroom safety in accordance with local needs and situations.
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