| Topic | Chapter-Section | Name of Videodisc Demonstration | Description |
|---|---|---|---|
| Descriptive Chemistry of Halogens | 4a | Light Initiated Bromination of Pentane | Bromine is added to 2 test tubes containing pentane. One tube is masked, and the other irradiated with light. The tube exposed to light looses the bromine color and pH paper shows evolution of an acidic gas. |
| Structure of 3 monobrominated isomeric products are shown. | |||
| Mechanism of free radical substitution is shown | |||
| 4b | Bromination of Hexane Isomers | Relative rates of reaction of 2 hexane isomers with bromine in light | |
| Mechanism of free radical bromination | |||
| 4c | Bromination of Alkyl Benzenes | Bromine is added to benzene, toluene, ethyl benzene, and isopropyl benzene. Order of reactivity parallels the stability of the free radical intermediates. | |
| Correlate with 8c -Reaction of Bromine with Benzene, Phenol, and Toluene | |||
| 6c | Addition of Iodine to alpha -Pinene - Relief of Ring Strain | reaction of alpha -pinene (from turpentine) with iodine results in a highly exothermic reaction accompanied by a large purple cloud of sublimation of excess iodine | |
| formerly used to treat infected horses' hooves | |||
| 7b | Spontaneous Combustion of Acetylene in Chlorine | Acetylene produced from reaction of calcium carbide and chlorine water bursts into flame and produces a copious amount of soot | |
| Combustion Reaction | |||
| 8b | Reaction of Bromine with Cyclohexane, Cyclohexene, and Benzene | Bromine reacts with the double bond of cyclohexene but not with alkanes or aromatic hydrocarbons. | |
| Addition reaction | |||
| 12c | Iodoform test for Methyl Ketones | Methyl ketones react with basic iodine to produce the solid iodoform. | |
| Use to illustrate the formation of trihalomethanes during the chlorination of public water supplies containing organic compounds such as humic acids. | |||
| 16e | Beilstein Test for Poly(vinyl chloride) | Bottles of poly(ethylene terphthalate) (PET) and poly(vinyl chloride) (PVC) are touched with a hot copper wire which is then placed in the flame of a Bunsen burner. After the wire is touched to the PVC bottle a green flame is produced indicating the presence of chlorine. A colorless flame results after touching the PET bottle. |
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