TopicChapter-SectionName of Videodisc DemonstrationDescription
Descriptive Chemistry of Halogens4aLight Initiated Bromination of PentaneBromine is added to 2 test tubes containing pentane. One tube is masked, and the other irradiated with light. The tube exposed to light looses the bromine color and pH paper shows evolution of an acidic gas.
Structure of 3 monobrominated isomeric products are shown.
Mechanism of free radical substitution is shown
4bBromination of Hexane IsomersRelative rates of reaction of 2 hexane isomers with bromine in light
Mechanism of free radical bromination
4cBromination of Alkyl BenzenesBromine is added to benzene, toluene, ethyl benzene, and isopropyl benzene. Order of reactivity parallels the stability of the free radical intermediates.
Correlate with 8c -Reaction of Bromine with Benzene, Phenol, and Toluene
6cAddition of Iodine to alpha -Pinene - Relief of Ring Strainreaction of alpha -pinene (from turpentine) with iodine results in a highly exothermic reaction accompanied by a large purple cloud of sublimation of excess iodine
formerly used to treat infected horses' hooves
7bSpontaneous Combustion of Acetylene in ChlorineAcetylene produced from reaction of calcium carbide and chlorine water bursts into flame and produces a copious amount of soot
Combustion Reaction
8bReaction of Bromine with Cyclohexane, Cyclohexene, and BenzeneBromine reacts with the double bond of cyclohexene but not with alkanes or aromatic hydrocarbons.
Addition reaction
12cIodoform test for Methyl KetonesMethyl ketones react with basic iodine to produce the solid iodoform.
Use to illustrate the formation of trihalomethanes during the chlorination of public water supplies containing organic compounds such as humic acids.
16eBeilstein Test for Poly(vinyl chloride)Bottles of poly(ethylene terphthalate) (PET) and poly(vinyl chloride) (PVC) are touched with a hot copper wire which is then placed in the flame of a Bunsen burner. After the wire is touched to the PVC bottle a green flame is produced indicating the presence of chlorine. A colorless flame results after touching the PET bottle.

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