Predominance-Zone Diagrams in Solution Chemistry: Dismutation Processes in Two-Component Systems (M-L)
A. Rojas-Hernández, M. T. Ramírez, I. González, and J. G. Ibáñez Universidad Autonoma Metropolitana-Iztapalapa, Departmento de Quimica, Apartado Postal 55-534, 09340 Mexico, D. F. Mexico
The application of the concept of dismutation in aqueous nonredox processes is discussed as well as its relationship to the corresponding chemical species distribution diagrams and predominance-zone diagrams for two-component systems. Examples discussed include the following systems: Cu(II)-NH3, H+-phosphates, Ag(I)-NH3, Zn(II)-NH3, Mn(II)-oxalates, and Fe(II)-o-phen. In addition, Charlot's scale for the prediction of reactions is explained together with his convention for the scale for predicting reactions as applied to the construction of predominance-zone diagrams.
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Rojas-Hernandez, A.; Ramirez, M. T.; Gonzalez, I.; Ibanez, J. G. J. Chem. Educ.1995 72 1099.
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