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  Home > JCE Print > Journal of Chemical Education > Issues > 1996  > April  >
General Interest
Relative Stabilities and Reactivities of Isolated Versus Conjugated Alkenes: Reconciliation Via a Molecular Orbital Approach
Chariklia Sotiriou-Leventis, Samir B. Hanna, and Nicholas Leventis
University of Missouri-Rolla, Rolla, MO 65409
Cover
April 1996
Vol. 73 No. 4
p. 295
Abstract
The well-accepted practice of generating a pair of molecular orbitals, one of lower energy and another of higher energy than the original pair of overlapping atomic orbitals, and the concept of a particle in a one-dimensional box are implemented in a simplified, nonmathematical method that explains the relative stabilities and reactivities of alkenes with conjugated versus isolated double bonds. In this method, Huckel-type MO's of higher polyenes are constructed by energy rules of linear combination of atomic orbitals. One additional rule is obeyed: bonding molecular orbitals overlap only with bonding molecular orbitals, and antibonding molecular orbitals overlap only with antibonding molecular orbitals.
More Information
*  Citation
 Sotiriou-Leventis, Chariklia; Hanna, Samir B.; Leventis, Nicholas. J. Chem. Educ. 1996 73 295.
*  Keywords
*  History
 Created:
Last Updated:		 9/23/1999
5/22/2006
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