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Unfortunately, a structure error appeared
in my article (J. Chem. Educ. 1997,
74, 1055-1059). Structure 5 should have been methyl
o-hydroxybenzoate (shown at right), and not
the methyl p-hydroxybenzoate shown in the
article. The boiling point given, 222 °C, is correct for
methyl salicylate (methyl o-hydroxybenzoate)
and this material is an oil under ambient
conditions with a freezing point of -8.6 °C. Methyl
p-hydroxybenzoate is a solid under ambient
conditions with a melting point of 131 °C, a
boiling point of 280 °C at 708 mm Hg, and no special
flavor attributes.
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