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Rudi von Eldik and Colin D. Hubbard, Eds. John Wiley:
New York, 1997. xii + 555 pp. Figs. and tables. 23.3
x 15.5 cm. $99.
Twelve teams or individuals contributed to this
book: J. J. Schneider, "Chemical Synthesis Using High
Temperature Species" (52 pp, 107 refs); C. D. Hubbard and R.
van Eldik, "Effect of Pressure on Inorganic Reactions" (50
pp, 205 refs); F. G. Klarner, M. K. Diedrich, and A. E.
Wigger (60 pp, 146 refs); J. Jurczak and D. T. Gryko, "Organic
Synthesis at High Pressure" (26 pp, 66 refs); "Inorganic and
Related Chemical Reactions in Supercritical Fluids" (30 pp,
77) refs; E. Dinjus, R. Fornika, and M. Scholz, "Organic
Chemistry in Supercritical Fluids" (54 pp, 192 refs); H.
Schmieder, N. Dahmen, J. Schon, and G. Wiegand (44 pp, 197 refs); T.
J. Mason and J. L. Luche, "Ultrasound as a New Tool for
Synthetic Chemists" (64 pp, 230 refs); G. J. Price,
"Applications of High Intensity Ultrasound in Polymer Chemistry (48
pp, 169 refs); M. R. Hoffman, L. Hua, R. Hochemer, D.
Willberg, P. Lang, and A. Kratel (50 pp, 146 refs); D. M. P. Mingos
and A. G. Whittaker, "Microwave Dielectric Heating Effects
in Chemical Synthesis" (36 pp, 102 refs); K. Heremans,
"Biomolecules Under Extreme Conditions" (30 pp, 74 refs).
It is indeed an unusually well-referenced book
(some entries have as many as 20 citations). The writing is
clear and remarkably uniform; one could easily imagine that
the entire book had been edited or even written by a single
person. The figures and structures have been carefully
drawn; this book deserves high marks for appearances. Nor is
it unusually expensive at $99.
While all of the topics have been reviewed separately
or in small groups, having them together in a single volume
was a good idea. No one is likely to read the book from cover
to cover, but anyone who is looking for one chapter and
inclined to browse may well find additional material to spike
his/her interest. I did not know very much about the cluster
chemistry described by Schneider, the sonochemistry by Mason
and Luche, or the microwave applications by Mingos
and Whittaker, and found it fascinating reading. It left me
wondering, in fact, why some additional possible topics had
not been included. Thus there is much interest in chemistry
at extremely low pressures such as prevail in the upper
atmosphere and interstellar space, in chemistry at extremely
low temperatures such as one encounters in inert gas solid
matrices, in chemistry in superacid media, in chemistry
induced by ionizing radiation, etc. Perhaps such topics might
be added in a follow-up volume at some future date.
There are also a few topics that are included more
than once. High pressure and supercritical media are
treated three times each. The individual chapters describe
different areas of chemistry, but the authors all feel the need
to start off with the fundamentals. This has resulted in
some duplication and even an occasional contradiction
(e.g., Chapter 6: "Supercritical fluidsare often extremely
good solvents"; Chapter 5: "Sadly, supercritical scientists
often manage to create the impression that supercritical
fluids are "wonder solvents" with almost magical powers ").
But these are the findings of minor faults. Hubbard
and van Eldik are capable and enthusiastic scientists, and they obviously recruited a team of coauthors who share their
approach and ability.
Klarner, Jurczak, Mason and Mingos all wrote
delightful chapters in this vein, as did the others. I enjoyed
leafing through the book and reading long stretches,
from Schneider's "high temperature synthesis techniques,
for which no classical synthesis counterpart exists"
to Heremans' "Bridgmanization", which he poses as a
possible future counterpoint to "Pasteurization" in
biotechnology. This book belongs in all chemistry libraries, and in not
a few private collections as well.
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