|
Mary Jo Nye. Twayne, An Imprint of Simon &
Schuster Macmillan: New York, 1996. 282 pp, 11 illus. ISBN
0-8057-9512-X. Cloth. $32.95.
Mary Jo Nye, Professor of Humanities and History
at Oregon State University, has, since at least 1972, been
publishing in the area of the history of science—in
particular, physics and chemistry. Her latest book goes at length
into the difficulties encountered by 19th century chemists
in working out relative atomic weights and the geometry
of bound carbon, and by physicists in coping with the
problems of the nature of light, whether heat was a fluid or
not, and the mechanical equivalent of heat, and problems
posed by magnetism and electricity. An example of the
mental blocks that had to be overcome is the author's quotation
of a French chemist's statement to his students in the
late 19th century that "bodies which are not volatile do not
have molecular weight", since their molecular weights could
not be determined by the Dumas method.
Because, presumably, of an irresistible hankering
after simplicity in nature it was early decided that the
formula for water, known to be 8/9 oxygen and 1/9
hydrogen by weight, just ought to be HO, and therefore oxygen
had atomic weight eight on a scale of hydrogen being one. It
is sobering to realize that all four of my grandparents
were born some ten years before the world's chemists (some
of them with considerable reluctance) made the switch
from OH to H2O, thus causing a chain reaction change in the
formulas of countless compounds.
To be honest, I, as an organic chemist, found this
book very heavily weighted toward physics. If you would like
to see the mathematics of Bohr's reasoning in working out
his picture of the atom, you will find it summarized here; if
you want a brief sketch of the thinking that led to
the Schrödinger wave equation, it is a few pages later. But
when we get to Grignard, he turns out to be a chemist who
got the Nobel Prize in 1912 (for what we are not told), and
got involved in war work several years later when he
"focussed on cracking heavy fractions of benzene to guarantee
a French source of toluene."
It was surprising to find that Wöhler's 1828
synthesis of ureasurely a landmark in changing the
philosophical thinking of chemistsis disposed of as having been an
"accidental synthesis" (quite correct!) with no further comment.
When we teach chemistry and physics at the
college level we simply have not got the time to go into the
tortuous stories of the false leads, false assumptions, postulates
that were followed up and turned out to be blind alleys, and
the stubborn human resistance to novel ideas that
characterized the development of chemistry and physics. But it is wise
for the teacher to be well aware of the kinds of pitfalls that
pioneers in science fell into. It should never be forgotten that
it was the ablest men and women of their age (am I
showing my prejudices?) who worked hard to get at the truth in
their respective fields, and there is not the slightest evidence
that the human IQ has improved an iota since 1800.
The book contains an excellent bibliography so that
the reader can find, in any good college library, plenty of
reading recommended by Nye on a wide variety of topics.
This book properly takes its place alongside the somewhat
similar (though it does not cover the same time period)
Fontana History of Chemistry by William Brock (reviewed in
J. Chem. Educ. 1994, 71, A214).
|