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  Home > JCE Print > Journal of Chemical Education > Issues > 1997  > June  >
Chemical Education Today
Letters
Stable Solutions for the Iodine Clock Reaction
George B. Kauffman and Charles R. Hall
California State University, Fresno, Fresno, CA 93740-0070

Cover
June 1997
Vol. 74 No. 6
p. 616

Full Text
The instability that has prevented the advance preparation of large quantities of solutions for a reproducible iodine clock reaction has led to modifications by Conway (1), Alyea (2), Kauffman and Hall (3), and most recently, Mitchell (4). In our modification of the solutions originally proposed by Alyea (5), instead of adding the sulfuric acid to the sodium sulfite-starch solution, we either added the acid to the potassium iodate solution or added it separately at the time of the demonstration as a third solution. In both cases, after standing for about a year in tightly closed containers, these solutions still produce instantaneous color changes.

Literature Cited

  1. Conway, W. J. J. Chem. Educ. 1940, 6, 398.
  2. Tested Demonstrations in Chemistry; Alyea, H. N.; Dutton, F. B., Eds.; Journal of Chemical Education: Easton, PA, 1965; p 130.
  3. Kauffman, G. B.; Hall, C. R. J. Chem. Educ. 1958, 35, 577.
  4. Mitchell, R. S. J. Chem. Educ. 1996, 73, 783.
  5. Alyea, H. N. J. Chem. Educ. 1955, 32, 9; Tested Demonstrations in Chemistry; Alyea, H. N.; Dutton, F. B., Eds.; Journal of Chemical Education: Easton, PA, 1965; p 19.
More Information
*  Citation
Kauffman, George B.; Hall, Charles R. J. Chem. Educ. 1997 74 616.
*  Keywords
*  History
Created:
Last Updated:
July 28, 1999
June 23, 2005
Link to Article added (August 2004).
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