A striking and beautiful demonstration of Le Chatelier's principle
is discribed by Cortel in Equilibrium with Fried
Eggs of PbI2 and KPbI3. If a crystal of
KI is placed on a Petri dish and a drop of Pb(NO3)2
solution is added, crystals of both PbI2and KPbI3
can form, making a "fried egg" with yellow PbI2 in the
center and white KPbI3 around the outside. The relative
sizes of the "white" and "yolk" can be varied by using larger or smaller
crystals of KI with the same volume of Pb(NO3)2
solution. As an exercise, you should predict whether the yolk or white
gets bigger as the size of the KI crystal increases. (The answer is
shown graphically within the article.)
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