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  Home > JCE Print > Journal of Chemical Education > Issues > 1997  > May  >
In the Classroom
The Coupling of Related Demonstrations to Illustrate Principles in Chemical Kinetics and Equilibrium
Richard A. Pacer
Department of Chemistry, Indiana Univ.-Purdue Univ., Fort Wayne Campus, Fort Wayne, IN 46805

Cover
May 1997
Vol. 74 No. 5
p. 543

Abstract
Two very simple lecture demonstrations, both involving the reaction of magnesium with one or more dilute acids, are linked together to illustrate principles in chemical kinetics and equilibrium.

In the first, crumpled Mg ribbon is placed in the nipple of a baby bottle holding 200 mL of 0.40 M HCl. The bottle is inverted into a large beaker of water, and the volume of H2 gas generated in one minute is measured. the experiment is repeated with 0.60 M HCl. The rate law, Rate = k[H+]n, is developed from the data.

In the second, equal lengths of Mg ribbon are placed in small beakers or Petri dishes, on an overhead projector, containing equal (0.80 to 1.0 M) concentrations of HCl, H3BO3, and CH3CO2H. Acids are not identified; students are merely told that 'Acids A, B, and C are of the same molarity.' Students are then asked to explain why the rates are so different, which serves as a lead-in for the instructor to explain the meaning of a Ka value. Students readily conclude that one of the acids must be a strong acid, but are puzzled by the other two. [The enormous difference in the Ka values of acetic and boric acids results in a striking difference in their reaction rates.]

More Information
*  Citation
Pacer, Richard A. J. Chem. Educ. 1997 74 543.
*  Keywords
Demonstrations, Introductory/High School Chemistry, Teaching/Learning Theory/Practice, Acid-Base Chemistry, Equilibrium, Kinetics
*  History
Created:
Last Updated:
July 28, 1999
June 23, 2005
  Home > JCE Print > Journal of Chemical Education > Issues > 1997 > May > Page 543


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