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  Home > JCE Print > Journal of Chemical Education > Issues > 1998  > August  >
In the Laboratory
Atomic Emission Spectra Using a UV-Vis Spectrophotometer and an Optical Fiber Guided Light Source
Manuel E. Minas da Piedade
Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, 1096 Lisboa Codex, Portugal

Mário N. Berberan-Santos
Centro de Química-Física Molecular, Complexo I, Instituto Superior Técnico, 1096 Lisboa Codex, Portugal

Cover
August 1998
Vol. 75 No. 8
p. 1013

Abstract
The use of an optical fiber guided light source in conjunction with a UV-Vis spectrophotometer to study the emission spectra of atomic hydrogen, sodium and helium in the undergraduate physical chemistry laboratory is described. The observed spectra have sufficient detail to allow an accurate calculation of the Rydberg constants and ionization energies of these elements. The obtained results also provide an opportunity to discuss energy level diagrams, selection rules for transitions, spin-orbit coupling magnitudes, and relative intensities of doublet lines.
More Information
*  Citation
Minas da Piedade, Manuel E.; Berberan-Santos, Mário N. J. Chem. Educ. 1998 75 1013.
*  Keywords
Physical Chemistry, Laboratory Instruction, Spectroscopy, Hydrogen, Sodium, Helium
*  History
Created:
Last Updated:
June 22, 1999
June 24, 2005
  Home > JCE Print > Journal of Chemical Education > Issues > 1998 > August > Page 1013


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