Laboratory Experiments on Electrochemical Remediation of the Environment. Part 4: Color Removal of Simulated Wastewater by Electrocoagulation-Electroflotation
Jorge G. Ibanez Departamento Ing. y C. Quimicas, Universidad Iberoamericana, 01210 Mexico, D. F. Mexico
M. M. Singh and Z. Szafran Department of Chemistry, Merrimack College, North Andover, MA 01845
Due to the large production of aqueous waste streams from textile mills and dye production plants, several processes have been under intense study. Electrochemical processes offer some distinctive advantages, including effects due to: 1) the production of electrolysis gases, and 2) the production of polyvalent cations from the oxidation of corrodible anodes (like Fe and Al). The gas bubbles can carry the pollutant to the top of the solution where it can be more easily concentrated, collected and removed. The metallic ions can react with the OH- ions produced at the cathode during the evolution of H2 gas to yield insoluble hydroxides that will adsorb pollutants out of the solution and also contribute to coagulation by neutralizing any negatively charged colloidal particles that might be present. In this experiment an iron electrode (paper clip) is used in conjunction with pH indicator dyes, so dramatic color changes will be noticed.
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Citation
Ibanez, Jorge G.; Singh, Mono M.; Szafran, Zvi. J. Chem. Educ.1998 75 1040.
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