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Geoff Rayner-Canham. W. H. Freeman: New York,
1996. 492 pp. ISBN: 0-7167-2819-2. $67.95.
There are plenty of good inorganic chemistry books
on the market, from venerable reference works (e.g., Cotton
and Wilkinson's Advanced Inorganic
Chemistry, Greenwood and Earnshaw's Chemistry of the
Elements) to "comprehensive" two-semester textbooks (e.g., Huheey,
Keiter, and Keiter's Inorganic Chemistry: Principles of Structure and
Reactivity, Douglas, McDaniel, and Alexander's
Concepts and Models of Inorganic Chemistry).
Undergraduate students, especially those new to inorganic chemistry,
frequently find these books overwhelming in depth and length (not to
mention weight!). Alternatively, some shorter books with less
ambitious goals present an oversimplified view of the field or sacrifice
conceptual material on behalf of sections on environmental,
industrial, or biological chemistry. Rayner-Canham's
Descriptive Inorganic Chemistry, a one-semester book aimed
specifically at the introductory (sophomore) level, provides an
excellent balance of theory and descriptive material, with a fresh
look at traditional and current areas of interest in inorganic
chemistry.
The first nine chapters (of a total of 21)
concisely present the fundamental concepts in inorganic
chemistry with unusually clear text, examples, and illustrations.
Included are chapters on covalent, metallic, and ionic bonding,
thermodynamics, acids and bases, and redox reactions. The rest
of the book deals separately with each group or block of
the periodic table. Interesting historic notes and anecdotes
and important biological aspects of the elements discussed are
included in each of these chapters. Most entertaining, a
number of current topics in inorganic chemistry, from
"bond-stretch isomers" and platinum anticancer drugs to the chemistry
of book preservation, are included in a few "boxed"
paragraphs throughout the book. Each chapter concludes with a
number of exercises, typically between 20 and 30, for which
the inclusion of solutions would have been desirable despite
the necessary increase in page count.
After using the textbook for a semester, I have
found very few factual errors in it; for example, the density of air
is given as 2.8 g L-1 instead of 1.293 g
L-1 (p 375). Even minor typographical errors, almost unavoidable in any first
edition, are also scarce: anthoquinone for anthraquinone (p
321), Moisson in lieu of Moissan (p 351), or Hindenberg
instead of Hindenburg (p 376). The display of a modern
periodic table on one of the inside covers, featured in many (if
not most) modern inorganic chemistry textbooks, would
have been a plus. Nevertheless, Rayner-Canham's is, overall,
one of the most readable inorganic chemistry textbooks
I have ever seen and I enthusiastically recommend it, especially
as an introductory book to the field.
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