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Oxford University
Press: New York, 1997. ISBN 0-19-885897-X. $60.00.
This short book is the first volume to appear in
the Oxford Chemistry Masters series, which will deal with
important topics, both established and developing, that a
senior-level or beginning graduate student might encounter for
the first time. To make the books accessible, little prior
knowledge of the topics will be required. A good foundation
in undergraduate chemistry will be assumed, however.
This volume deals specifically with two powerful,
independent but often complementary, topics: circular
dichroism (CD), which deals with the differential absorption of
left-handed and right-handed circularly polarized light by
optically active molecules, usually involving electronic
transitions in the visible and ultraviolet regions of the
electromagnetic spectrum; and linear dichroism (LD), which deals with
the differential absorption of linearly polarized light
(really a superposition of left-handed and right-handed
circularly polarized light) of oriented molecules, not necessarily
optically active, parallel and perpendicular to the orienting axes.
Although these techniques have usually been applied to the study
of organic and biological molecules, they are also very
useful for the study of inorganic compounds, as demonstrated
in this book.
The book is divided into seven sections (plus
four appendices) and contains material on elementary topics,
CD of biomolecules, LD of biomolecules and small
molecules, CD of electric dipole allowed and magnetic dipole
allowed transitions, magnetic CD, and CD formalism.
The authors, Alison Rodger and Bengt Norden, who
are acknowledged experts and practitioners of these
methodologies, have nicely followed the philosophy of the series as
described in the first paragraph. They assume no prior knowledge
of CD and LD and their writing is clear and concise. The
first two or three chapters are largely qualitative in nature,
while the latter ones are presented with increasing
mathematical rigor. A good working knowledge of trigonometry,
vectors, complex numbers, matrices, quantum mechanics and its
associated mathematics, and some group theory is needed
to benefit fully from the well-presented material in each of
the latter chapters.
The book presents a wealth of information in an
attractive, readable fashion. The drawings, figures, and graphs
are clearly presented-a requirement for topics where
geometry plays such a critical role. I particularly enjoyed reading
about the diverse methods used to orient molecules for LD
(photoselection, surprisingly, was not described), the tricks of
the trade for obtaining high-quality CD spectra, the octant
rule, and exciton CD, one of the few methods for obtaining
the absolute configuration of an optically active molecule. I
was also pleased to find the book to be almost free of errors
(only a dozen and a half or so)-which is essential for any
book claiming to be a textbook.
I believe that the authors have succeeded in their
objective of writing a concise, readable, eye-pleasing, but
mathematically rigorous book on CD and LD. Anyone, student or
even professor, who reads this book with care and diligence
will then have the competence to rigorously apply CD and
LD to chemical problems.
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