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  Home > JCE Print > Journal of Chemical Education > Issues > 1998  > September  >
Information • Textbooks • Media • Resources
JCE Online: Mathcad in the Chemistry Curriculum
The Iodine Spectrum: IodineSpectrum.mcd
George Long
Department of Chemistry, Indiana University of Pennsylvania, Indiana, PA 15705

Theresa Julia Zielinski
Department of Chemistry, Medical Technology, and Physics, Monmouth University, West Long Branch, NJ 07764-1898

Cover
September 1998
Vol. 75 No. 9
p. 1192
Abstract
The goal of this document is to present a systematic development of the relationship between spectroscopic experiments and the determination of molecular bond lengths in the excited state of diatomic molecules for which a high resolution vibronic spectrum is available. This document can serve as a template for students to use for data analysis of the UV-vis spectrum of I2 or other diatomic gases. Use of this document as a template requires student UV-vis spectral data acquired in the laboratory. Faculty can also use this document with the enclosed sample data for student practice when an instrument is not available. The details of the Birge-Sponer plot are clearly illustrated. The document discusses the Morse potential and includes calculations with this potential function using correct units. Students can see clearly the mathematical steps leading to the calculation of the equilibrium bond length of the excited state of iodine. The Morse potentials for both the ground state and excited state permit discussion of the effect of excitation on molecular geometry. This document represents a way to make data analysis and work with the concepts for this experiment more efficient for students. Student exercises are fully integrated into the presentation and implementation of the mathematical concepts of this topic. References for the laboratory experiment are included.


Ground and excited electronic state Morse potentials from IodineSpectrum.mcd.

More Information
*  Citation
 Long, George; Zielinski, Theresa Julia. J. Chem. Educ. 1998 75 1192.
*  Keywords
 teaching, learning aids, physical chem, quantum chem, internet
*  History
 Created:
Last Updated:		 June 21, 1999
June 24, 2005
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