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The Fourier transform is used in many
instrumental techniques, including infrared spectroscopy, NMR, and
mass spectrometry. Although most instruments perform this
mathematical technique transparently, an understanding of
how it works is important. This understanding will help
instrument users set appropriate parameters, appreciate the
limitations of an instrument, and obtain better spectra. This
document simultaneously introduces students to how the
Fourier transform works and how various instrument parameters
affect the results of the Fourier transform. Waveforms are
produced and integrated using sine waves, cosine waves,
and simple functions. The fast Fourier transform is used
with simulated data to introduce students to the relationship
between the signal waveform and the signal frequency of a
spectrum. Students are then led to the concepts of dwell
time and resolution through a series of interactive exercises.
The document ends with an introduction to the Fourier
transform of decaying signals. Students and teachers may
use IntroFourierTransform.mcd as written, or teachers may
remove some graphs to increase discovery learning and
class discussion. IntroFourierTransform.mcd includes
substantial student interaction by changing variables and written
reflection exercises. The companion document, LectureIntroFT.mcd,
designed for instructors to use interactively during lecture,
is the abbreviated version of IntroFourierTransform.mcd.
These Mathcad documents build on previously published
work, Using Mathcad to Teach Instrumental Techniques;
J. Chem. Educ. 1998, 75, 375.
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