Electrochemistry can be one of the more difficult subjects in chemistry, especially for high school students. Tools are needed to help illustrate the practical use of the Nernst equation, half-cell voltages, redox reactions, etc. Instructions for the preparation of a Ag/AgCl "reference"-type electrode that uses a gel-type matrix are given. The construction steps for the reference electrode have been used successfully by our students to construct their own electrodes. In addition, construction steps are provided for a very sturdy Pt-nichrome "inert" electrode, which can be used many times. Together, these two electrodes, along with a multivoltmeter, have been used successfully by our students to determine the percent of iron in Fe(NH4)2(SO4)2 and in Fe2O2 unknowns purchased commercially.
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