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  Home > JCE Print > Journal of Chemical Education > Issues > 1999  > June  >
In the Laboratory
A Puzzling Alcohol Dehydration Reaction Solved by GC–MS Analysis
Michael W. Pelter and Rebecca M. Macudzinski
Department of Chemistry and Physics, Purdue University Calumet, Hammond, IN 46323
Cover
June 1999
Vol. 76 No. 6
p. 826

Abstract
We have adapted the dehydration of 2-methyl-2-propanol to a "puzzle" approach for use in our second-semester chemistry major organic laboratory. The reaction of 2-methyl-2-propanol with ˜50% sulfuric acid at 100 °C yields isobutylene, which reacts further by a "puzzling" reaction. By coupling the GC–MS analysis of the product mixture with their knowledge of the mechanism of alcohol dehydration and alkene reactivity, students are able to identify the major products of this reaction.
More Information
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Citation
Pelter, Michael W.; Macudzinski, Rebecca M. J. Chem. Educ. 1999, 76, 826.
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Keywords
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History
Created:
Last Updated:
6/11/2008
6/13/2008
  Home > JCE Print > Journal of Chemical Education > Issues > 1999  > June  > Page 826


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