Often in physical chemistry courses, the direct proof of Stirling's approximation is omitted owing to the complexity of the mathematics involved. We present an accessible proof of this result that requires only an understanding of first-year calculus. We also present an undergraduate project dealing with the validity of Stirling's approximation. This assignment asks students to study the validity of the formula using mathematical tools such as programmable calculators, commercially available computer software such as Derive, and basic computer programming. Examples of students' solutions are provided.
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Citation
Wallner, Anton S.; Brandt, Keith A. J. Chem. Educ.1999 76 1395.
Keywords
Physical Chemistry; Curriculum; Chemical Education Research; Statistical Mechanics; Teaching/Learning Theory/Practice
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