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  Home > JCE Print > Journal of Chemical Education > Issues > 2000  > July  >
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A More Pedagogically Sound Treatment of Beer's Law: A Derivation Based on a Corpuscular-Probability Model
William D. Bare
Department of Chemistry, University of Virginia, Charlottesville, VA 22904-4319

Cover
July 2000
Vol. 77 No. 7
p. 929

Abstract
An argument is presented which suggests that the commonly seen calculus-based derivations of Beer's law may not be adequately useful to students and may in fact contribute to widely held misconceptions about the interaction of light with absorbing samples. For this reason, an alternative derivation of Beer's law based on a corpuscular model and the laws of probability is presented. Unlike many previously reported derivations, that presented here does not require the use of calculus, nor does it require the assumption of absorption properties in an infinitesimally thin film. The corpuscular-probability model and its accompanying derivation of Beer's law are believed to comprise a more pedagogically effective presentation than those presented previously.
More Information
*  Citation
Bare, William D. J. Chem. Educ. 2000 77 929.
*  Keywords
Analytical Chemistry; Beer's Law; Quantitative Analysis; Textbooks; UV-Vis Spectroscopy
*  History
Created:
Last Updated:
June 2, 2000
April 15, 2005
  Home > JCE Print > Journal of Chemical Education > Issues > 2000 > July > Page 929


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