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  Home > JCE Print > Journal of Chemical Education > Issues > 2000  > November  >
Chemical Education Today
Letters
Interpretation of Second Virial Coefficient: Author Reply
Jaime Wisniak
Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva, Israel

Cover
November 2000
Vol. 77 No. 11
p. 1409

Full Text
The author replies to Utgikar

I agree with Utgikar that the equation of state PV = nRT represents the definition of an ideal gas, according to the macroscopic viewpoint (no assumptions regarding the structure of matter). Nevertheless, there are several situations where some properties of a real gas are identical to those of the ideal gas. As stated in the paper, at Boyle's temperature and sufficiently low pressures, the virial equation of state becomes PV = RT, although some of the properties of the gas are different from those of the ideal gas. Similarly, at temperature TH the enthalpy becomes independent of the pressure, although the gas is not ideal. Perhaps the message would be clearer if we write PV approximately equal to RT, to keep the strict definition of an ideal gas.

More Information
*  Citation
Wisniak, Jaime. J. Chem. Educ. 2000 77 1409.
*  Keywords
Chemical Engineering; Gases; Physical Chemistry; Thermodynamics
*  History
Created:
Last Updated:
October 6, 2000
April 15, 2005
  Home > JCE Print > Journal of Chemical Education > Issues > 2000  > November  > Page 1409


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