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  Home > JCE Print > Journal of Chemical Education > Issues > 2000  > October  >
Information • Textbooks • Media • Resources
Computer Bulletin Board
Comparisons and Demonstrations of Scientific Calculators
Myung-Hoon Kim
Department of Sciences, Georgia Perimeter College, Dunwoody Campus, Dunwoody, GA 30338-4497

Suw-Young Ly
Department of Fine Chemistry, Seoul National University of Technology, Seoul 139-743, Korea

Tae-Kee Hong
Department of Chemistry, Hanseo University, Seosan, Choongnam 356-820, Korea

Cover
October 2000
Vol. 77 No. 10
p. 1367

Abstract
Scientific calculators are classified into four types: Basic, Intermediate, Advanced-I, and Advanced-II. They are compared in terms of their capacities, featuring many advantages of the graphic calculator over simple nongraphic calculators. Built-in software packages with the advanced calculators include graphing programs, an equation solver with numerical methods, matrix algebra for solving simultaneous equations, and advanced statistics including a nonlinear least squares regression. Applications in this paper include a simulation of acid-base titration curves, and graphic display of a time course of concentrations of reactants and products for a chemical reaction with first-order kinetics. Ready demonstrations of graphic results from a quantitative chemical problem are particularly advantageous with the advanced graphic calculators.
Supplement

Acid-Base Titration Curve with a Graphic Calculator

This is a source program to generate an acid-base titration curve with the model TI-85 graphing calculator. Helpful explantions are given in parentheses. Some editing or minor modifications might be necessary to be useful for other types of calculators from different manufacturers.

:ClDrw clear a previous drawing on the screen
:0.00 -> xMin set a lower limit for the volume of the base, VB
:50.0 -> xMax set an upper limit for the volume of the base
:5.00 -> xScl tick marks in the x-axis for the volume
:0.00 -> yMin set a lower limit for the pH
:14.0 -> yMax set an upper limit for the pH
:1.00 -> yScl tick marks in the y-axis for the pH
:25.0 -> VA input of the volume of the acid
:0.100 -> MA input of the concentration of the acid
:0.100 -> MB input of the concentration of the base
:10E-14 -> KW input of the ion-product of water
:CA=MA*VA/(VA+x) calculate total concentration of the acid in the mixture at any time during the titration)
:CB=MB*x/(VA+x) calculate total concentration of the base in the mixture
:PH=-log(0.5((CA-CB)+
((CA-CB)2+4KW)^0.5))
calculate pH according to the general formula
:y1=PH store the calculated pH values into an array of variable y1
:DrawF y1 draw a function y1
:End

Notes:

  1. TI-80, TI-81, TI-82, and TI-83 do not allow a variable name with two charactors. Thus , MA, MB, VA, CA, CB , KW and PH must be changed to a single character such as M, N, V, A, B, K and P, respectively for those TI models.
  2. Values for MA, MB, and VA can be readily changed to other values if titration at other conditions are desired.
  3. This work and other related work with graphic calcualtors were presented at the 14th Biennial Conference on Chemical Education, Clemson University, Clemson, SC, August 4-8, 1996.

(tit_asc.htm, 10/98, animated, MHK)

*  Contents
*  Download
More Information
*  Citation
Kim, Myung-Hoon; Ly, Suw-Young; Hong, Tae-Kee. J. Chem. Educ. 2000 77 1367.
*  Keywords
Acid-Base Chemistry; Graphic Calculator; Kinetics; Teaching / Learning Aids; Titration; Computer Assisted Instruction
*  History
Created:
Last Updated:
September 22, 2000
August 31, 2005
  Home > JCE Print > Journal of Chemical Education > Issues > 2000  > October  > Page 1367


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