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The first edition of this text by two chemistry
professors at St. Olaf College, Northfield, MN, appeared in 1991
but was not reviewed in this Journal. As in the earlier
edition, the authors emphasize molecular orbitals and symmetry
to explain many aspects of the bonding, structure, and
reactivity of inorganic compounds. The new edition is one-third
longer than the first (480 pp). In contrast to more
traditional "encyclopedic" texts (e.g., Cotton and Wilkinson's
Advanced Inorganic Chemistry or Greenwood and Earnshaw's
Chemistry of the Elements), which present the descriptive chemistry of
the elements according to periodic table groups, it is a
balanced blend of theory and facts, organized on a topical basis.
However, considerable descriptive chemistry is integrated into
the book's chapters, many of which begin with historical
background material.
In addition to selecting what they consider the
most appropriate and interesting topics for an upper-level
undergraduate inorganic course, Miessler and Tarr have once
again succeeded in making their text accessible to students
by increasing the number of examples and exercises within
the chapters. Answers to the examples are included in the
chapters themselves, while answers to the 90 exercises are relegated
to one of the 9 appendices (the other appendices present
valuable data - ionic radii; ionization energy; electron
affinity; Pauling electronegativities; absolute hardness parameters;
CA, EA, CB, and EB values; character tables; and
electron-dot diagrams and formal charge).
Numerous problems (338 in all) conclude all chapters
except the first; answers are not provided, so they may
be assigned as homework. To encourage use of the literature
by both students and instructors the authors have retained
the extensive references in the first edition, many to historical
or classic papers or books, and they have increased the
number of problems taken from recent articles. References cited
in the text (some as recent as 1998) appear at the bottom
of the pages, while general references are given in single
paragraphs just before the problems. Numerous equations
and reaction schemes, 361 figures, and 132 tables are
provided. An extremely detailed index (7 quadruple-column pages
in small type) facilitates location of material.
The scope of the text can be seen from the titles of
its 16 chapters: Introduction to Inorganic Chemistry,
Atomic Structure, Simple Bonding Theory, Symmetry and
Group Theory, Molecular Orbitals, Acid-Base and
Donor-Acceptor Chemistry, The Crystalline Solid State (new to this
edition), Chemistry of the Main Group Elements,
Coordination Chemistry (four chapters on Structures and Isomers,
Bonding, Electronic Spectra, and Reactions and Mechanisms),
Organometallic Chemistry, Organometallic Reactions and
Catalysis, Parallels Between Main Group and Organometallic
Chemistry, and Bioinorganic and Environmental Chemistry.
I am pleased to recommend heartily this thoroughly
updated and revised edition of a relatively brief and
user-friendly survey of inorganic chemistry, with its strong coverage
of molecular symmetry and group theory as well as
inclusion of important and chemically and socially relevant topics.
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