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Millennia ago civilizations such as those in Egypt
and Mesopotamia invented geometry for practical reasons.
They wanted to redetermine, for example, the boundaries of a
field after a flood had abated. The classical Greeks as
exemplified by Archimedes and Euclid, on the other hand, were
driven by curiosity and developed geometry for its own sake.
Regardless of how it originated, it is fair to say that this
idealized and still very useful Euclidean geometry deals with objects
and functions that have smooth edges, lines and surfaces.
Objects in the real world are rarely ideal, however.
Several decades ago Mandelbrot invented a geometry
to deal with "rough" edges, lines, and surfaces, which he
called fractal geometry. In this geometry, which is well suited
to deal with many real--and abstract--objects, non-integer
(i.e., fractional) dimensions occur. Scientists realized
immediately that they could profitably apply this new paradigm to a
large number of previously poorly understood phenomena.
The success of this approach is underscored by the dozens of
books on fractals that have been written in the intervening
period, covering topics such as geology, botany, physics,
astronomy, environmental science, and, not surprisingly, chemistry.
Rothschild's Fractals in
Chemistry is the latest book on fractals devoted to chemistry. This small, attractive,
almost error-free volume is divided into eight chapters, each
richly adorned with figures and equations and an extensive
tabulation of notes and references for further reading, and three
appendices and two glossaries. The subject matter is diverse,
dealing with, for example, fractal theory, a necessity for a book devoted
to the applications of fractals, adsorption, porosity,
aggregation, kinetics, diffusion, spectroscopy, photochemistry, and
chemical degradation. As these topics suggest, the book is very
physically oriented.
If one is looking for a leisurely-paced or
watered-down book on fractal applications, this book is not for you. It
is concisely written and aimed at professional chemists
interested in learning how fractals may be useful in their
research and graduate students with considerable experience in
physical chemistry. It covers a large number of topics, only some
of which may be familiar to the reader. A reader must
be prepared to learn the methods and terminology of fractal
geometry, which may seem strange and off-putting at first, and of
each topic under consideration.
The author, who clearly loves this subject, brings
much to this book. He is authoritative and practical and writes
well. He never hesitates to tell the reader what published
results really mean and when a given method has been oversold.
He chooses carefully his examples and the close to one
hundred figures, most of which have come from the chemical
literature. (The figures are, in my opinion, the highlight of the
book.) The author presents many mathematical equations not
for their own sake but to help the reader master the principles
by which fractal methodology can be applied to real problems.
This book is an interesting addition to the fractal
literature. If you are seeking a concise, up-to-date,
authoritative, practical guide to fractal applications in chemistry,
consider it seriously. Keep in mind, however, that it will make
considerable demands on you.
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