The reaction of white phosphorus with pure oxygen is conveniently and safely demonstrated by carrying out the reaction in a retort that has its open end submerged in water. After filling the retort with oxygen gas, a small amount of white phosphorus is introduced and heated with a hot-plate until it ignites. The spectacular reaction leads to consumption and expulsion of oxygen gas, creation of a partial vacuum in the retort, and back suction of water that extinguishes the combustion.
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Citation
Keiter, Richard L.; Gamage, Chaminda P. J. Chem. Educ.2001 78 908.
Keywords
Demonstrations; Descriptive Chemistry; General Chemistry; Inorganic Chemistry; Luminescence; Main-Group Elements; Phosphorus; Redox Reactions; Teaching / Learning Aids
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