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Spectroscopy is both fundamentally and practically important to chemistry.
However, the complicated mathematics makes the topic difficult to understand,
and an easy-to-read text that makes the subject comprehensible is overdue.
Basic Atomic and Molecular Spectroscopy achieves this goal by covering
the basic concepts of both quantitative and qualitative spectroscopy
while avoiding a significant portion of the mathematical aspects of the
subject. By omitting most of the thorny mathematics, the author succeeds
in making spectroscopy comprehensible. The target audience is first-
or second-year students in a British University, but the text is well
suited for any student, researcher, or professional with minimal mathematics
qualifications.
The theories of spectroscopy are covered in the first
100 pages of the book. First, a very basic explanation of spectroscopy
and the electromagnetic
spectrum is presented. Then, using the emission spectrum of hydrogen,
the concept of quantization of energy and the quantum mechanics that
describes this emission pattern is developed. In the traditional manner,
the electronic structure theory for the hydrogen atom is extended to
poly-electronic atoms and then to the electronic structure of diatomic
and polyatomic molecules. The theories of molecular vibrations and rotations
(within the Born–Oppenheimer approximation) follow.
The remainder
of the text covers the practice of spectroscopy. Chapter Eight describes
the instrumentation for obtaining microwave, infrared,
visible, and ultraviolet spectra and is followed by a series of chapters
that describe each type of spectroscopy in detail. Rotational spectroscopy
is discussed first. Vibrational spectroscopy follows with a surprisingly
rather-thorough treatment of Raman spectroscopy. The book ends with the
treatment of electronic spectroscopy that, for the most part, focuses
on vibrational and rotational structure of various electronic states.
Overall,
the book is well laid out and attractively typeset. There are a number
of shaded boxes containing supplementary material that can be
omitted on a first reading. Included in these shaded boxes are thoroughly
worked example problems that relate directly to topics discussed in the
text. Margin notes that clarify points made in the main reading are numerous.
Important vocabulary words are highlighted throughout the reading, but
the meanings of these ‘important’ words are not always easily
inferred from the context. Each chapter includes a list of aims, summary
of key points, and problems (with solutions); all represent the material
well. However, the amount of space allocated to the objectives and summaries
for each chapter make up a rather high percentage of the total text,
and the numbers of problems at the end of each chapter are few.
Taken
as a whole, the content is somewhat incomplete, which isn’t
surprising considering the length of the book. Although the fundamental
aspects of spectroscopy are covered well, the text is lacking in practical
applications. Spectral interpretation is confined to an abbreviated table
with “typical” IR spectral positions with no discussion on
how these positions can be used to deduce molecular structure. Quantitative
spectroscopy is limited to a brief discussion of the Beer–Lambert
law and its application to electronic absorption. The reader is only
exposed to rotational, vibrational, electronic, and Raman spectroscopy;
there is no mention of atomic absorption (or emission), NMR, ESR, photoelectron,
or other spectroscopies. In particular, the exclusion of NMR is a serious
deficiency of the text.
Despite the brief coverage of the topic, the
clear explanations and affordable price make this book an ideal primer
for
students, researchers, and professionals.
Because the book is written for first- or second-year students, it
is not suitable as a primary or secondary text in upper-level chemistry
courses. However, faculty who want to introduce lower-level students
to spectroscopy will find this text to be practical. The book is also
well suited for independent study since it is easy to read, includes
thoroughly worked example problems, and is short enough to be covered
in a few weeks. Readers of this text will feel as if they really understand
what they have read and will appreciate the writing style of the author.
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