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  Home > JCE Print > Journal of Chemical Education > Issues > 2004  > December  >
In the Laboratory
A Laser-Pointer-Based Spectrometer for Endpoint Detection of EDTA Titrations
Christopher E. Dahm and James W. Hall
Department of Chemistry and Physics, Wingate University, Wingate, NC 28174

Brian E. Mattioni
Department of Chemistry, The Pennsylvania State University, University Park, PA 16802

Cover
December 2004
Vol. 81 No. 12
p. 1787

Abstract
A simple laser-pointer-based spectrometer has been developed for endpoint detection of EDTA titrations of magnesium and calcium. This spectrometer was built to decrease the uncertainty in determining the endpoint of titrations performed with a Calmagite indicator. With a photoresistor as the detector, and with the aid of a voltage-divider circuit, the quantity of light being absorbed can be followed with a simple pH–voltmeter. Students determine the endpoint by graphing the data and applying simple mathematics. Beer–Lambert studies with the spectrometer also show excellent agreement for a given set of solutions.
Supplement
Instructions for the students and notes for the instructor are available.
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More Information
*  Citation
Dahm, Christopher E.; Hall, James W.; Mattioni, Brian E. J. Chem. Educ. 2004 81 1787.
*  Keywords
Analytical Chemistry; Calcium; Dyes; General Chemistry; Laboratory Equipment / Apparatus; Laboratory Instruction; Lasers / Laser Spectroscopy; Magnesium; Titration / Titrimetry
*  History
Created:
Last Updated:
November 1, 2004
November 9, 2004
  Home > JCE Print > Journal of Chemical Education > Issues > 2004  > December  > Page 1787


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