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  Home > JCE Print > Journal of Chemical Education > Issues > 2004  > November  >
Research: Science and Education
Examples for Non-Ideal Solution Thermodynamics Study
Carl W. David
Department of Chemistry, University of Connecticut, Storrs, CT 06269-3060
Cover
November 2004
Vol. 81 No. 11
p. 1655
Abstract
A tractable example of a non-ideal solution that allows analytical evaluation of thermodynamically interesting functions and verification of various relationships normally derived in physical chemistry class is presented. A partition function representing a mixture of hard spheres that suffer from non-ideality is used to recover an equation of state, the Gibbs and Helmholtz free energies, the partial molal volumes, and the chemical potentials. Euler's theorem for the volume and the Gibbs energy are demonstrated.
More Information
*  Citation
 David, Carl W. J. Chem. Educ. 2004 81 1655.
*  Keywords
 Physical Chemistry; Solutions / Solvents; Theoretical Chemistry
*  History
 Created:
Last Updated:		 September 27, 2004
October 4, 2004
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