This article covers the background and related science associated with a thermochromic
window. A thermochromic window is a device that changes its reflectance and
transmission properties at a specific critical temperature. At this temperature
the material undergoes a semiconductor-to-metal transition—at low temperature
the window will let in all of the sun's energy while above the critical temperature
it will reflect the infrared portion of the sun's energy. Hence a thermochromic
window could be used to significantly reduce air conditioning costs, which
has consequential positive benefit in reducing electricity consumption and
hence green house gas emissions. This article details the underlying science
in making a new thin-film thermochromic coating by chemical vapor deposition;
it describes the underlying physical chemistry associated with the semiconductor-to-metal
transition and shows how substitutional doping within a crystal lattice can
be used to lower the thermochromic switching temperature.
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Citation
Parkin, Ivan P.; Manning, Troy D. J. Chem. Educ.2006 83 393.
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