This Mathcad document allows students to explore the characteristics of the components of the angular electronic wave function of the hydrogen atom, Ylm(Θ, φ). Within this exercise, Ylm(Θ, φ) is separated into three parts: the normalization constant, a polynomial function and an exponential function. After choosing quantum numbers l and m, users can evaluate and graphically display the component functions of Ylm(Θ, φ) separately. After combining these components, the entire wave function is constructed and a graph of its associated probability density is displayed. Users have the opportunity to discover when, why and how linear combinations of the exponential portion of Ylm(Θ, φ) are used in constructing orbital plots that are normally displayed in textbooks. In addition, students gain a mathematical understanding of why the quantum number m can only vary from −l to l.
The first five Legendre Polynomials, Leg(order,x) as a function of x.
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