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  Home > JCE Print > Journal of Chemical Education > Issues > 2008  > April  >
In the Laboratory
Green Chemistry
"Greening Up" the Suzuki Reaction
Evangelos Aktoudianakis, Elton Chan, Amanda R. Edward, Isabel Jarosz, Vicki Lee, Leo Mui, Sonya S. Thatipamala, and Andrew P. Dicks
Department of Chemistry, University of Toronto, Toronto, Ontario M5S 3H6, Canada
Cover
April 2008
Vol. 85 No. 4
p. 555
Abstract
This article describes the rapid, green synthesis of a biaryl compound (4-phenylphenol) via a Pd(0)-catalyzed Suzuki cross-coupling reaction in water. Mild reaction conditions and operational simplicity makes this experiment especially amenable to both mid- and upper-level undergraduates. The methodology exposes students to purely aqueous microscale organic reactivity and showcases topical research in the milieu of an industrially applicable process.

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Citation
Aktoudianakis, Evangelos; Chan, Elton; Edward, Amanda R.; Jarosz, Isabel; Lee, Vicki; Mui, Leo; Thatipamala, Sonya S.; Dicks, Andrew P. J. Chem. Educ. 2008, 85, 555.
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Keywords
Aromatic Compounds; Catalysis; Green Chemistry; Hands-On Learning / Manipulatives; Laboratory Instruction; Microscale Lab; Organic Chemistry; Phenols; Second-Year Undergraduate; Upper-Division Undergraduate; Water / Water Chemistry
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History
Created:
Last Updated:
2/26/2008
3/5/2008
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Experiments, laboratory exercises, lecture demonstrations, and other descriptions of the use of chemicals, apparatus, instruments, computers, and computer interfaces are presented in the Journal of Chemical Education as illustrative of new or improved ideas or concepts in chemistry instruction and are directed at qualified teachers. Although every effort is made to assure and encourage safe practices and safe use of chemicals, the Journal of Chemical Education cannot assume responsibility for uses made of its published materials. Many chemicals are hazardous. Precautions for the safe use of hazardous chemicals and directions for their proper disposal are described in the Material Safety Data Sheets and on the labels. We strongly urge all those planning to use materials from our pages to make choices and to develop procedures for laboratory and classroom safety in accordance with local needs and situations.
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