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  Home > JCE Print > Journal of Chemical Education > Issues > 2008  > January  >
In the Laboratory
A Simple Rate Law Experiment Using a Custom-Built Isothermal Heat Conduction Calorimeter
Lars Wadsö
Division of Building Materials, Lund University, 221 00 Lund, Sweden

Xi Li
Applied Chemistry, Wuhan University of Technology, Wuhan, Hubei, China

Cover
January 2008
Vol. 85 No. 1
p. 112

Abstract
Most processes (whether physical, chemical, or biological) produce or consume heat: measuring thermal power (the heat production rate) is therefore a typical method of studying processes. Here we describe the design of a simple isothermal heat conduction calorimeter built for use in teaching; we also provide an example of its use in simultaneously determining the rate constant and the reaction enthalpy of the first-order base hydrolysis of propyl parabene.
Supplement
Instructions for calibration of isothermal calorimeters, a teacher's guide, and a student's guide are available.
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Citation
Wadsö, Lars; Li, Xi. J. Chem. Educ. 2008, 85, 112.
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Keywords
Calorimetry / Thermochemistry; Graduate Education / Research; Physical Chemistry; Rate Law; Thermodynamics; Upper-Division Undergraduate
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History
Created:
Last Updated:
12/4/2007
12/12/2007
  Home > JCE Print > Journal of Chemical Education > Issues > 2008  > January  > Page 112


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