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  Home > JCE Print > Journal of Chemical Education > Issues > 2009  > August  >
In the Laboratory
Permeation of Adsorbable and Non-Adsorbable Gases in Microporous Zeolite Membranes
Patrícia F. Lito, Ana L. Magalhães, and Carlos M. Silva
CICECO, Departamento de Química, Universidade de Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal

Daniel L. A. Fernandes
CESAM, Departamento de Química, Universidade de Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal

Cover
August 2009
Vol. 86 No. 8
p. 976

Abstract
A simple experiment is described to study the permeation of adsorbable and non-adsorbable gases through microporous membranes. The permeation fluxes of nitrogen and carbon dioxide through a zeolite membrane are measured at two temperatures for different trans-membrane pressure drops. Single gas permeances and the corresponding ideal selectivities are calculated as function of the pressure drop. Based on the experimental results, students are able to identify and discriminate transport mechanisms occurring in porous media and gain insight on fundamentals of membrane and diffusion processes.
Supplement
Formulas of the flux equations for the various transport mechanisms; List of gases, materials, and equipment used; Two figures showing a simplified layout and a detailed drawing of the membrane module
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Citation
Lito, Patrícia F.; Fernandes, Daniel L.A.; Magalhães, Ana L.; Silva, Carlos M. J. Chem. Educ. 2009, 86, 976.
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Keywords
Analytical Chemistry; Chemical Engineering; Gases; Hands-On Learning / Manipulatives; Laboratory Equipment / Apparatus; Laboratory Instruction; Membranes; Separation Science; Transport Properties; Upper-Division Undergraduate
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History
Created:
Last Updated:
6/16/2009
6/30/2009
 Caution! 
Experiments, laboratory exercises, lecture demonstrations, and other descriptions of the use of chemicals, apparatus, instruments, computers, and computer interfaces are presented in the Journal of Chemical Education as illustrative of new or improved ideas or concepts in chemistry instruction and are directed at qualified teachers. Although every effort is made to assure and encourage safe practices and safe use of chemicals, the Journal of Chemical Education cannot assume responsibility for uses made of its published materials. Many chemicals are hazardous. Precautions for the safe use of hazardous chemicals and directions for their proper disposal are described in the Material Safety Data Sheets and on the labels. We strongly urge all those planning to use materials from our pages to make choices and to develop procedures for laboratory and classroom safety in accordance with local needs and situations.
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