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  Home > JCE Print > Journal of Chemical Education > Issues > 2009  > October  >
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Chemical Education Today
Letters
More About the Periodic Table
Michael Laing
Durban 4001, South Africa
Cover
October 2009
Vol. 86 No. 10
p. 1189

Full Text
I found the letter by William B. Jensen about the periodic table most interesting (1), especially his Figure 1, the “periodic table” from Ephraim’s textbook labeled as “Periodisches System der Elemente”. I have an English translation of the 6th edition dated 1954 (2), in which “The Periodic Classification” table now treats elements 57 to 71 slightly differently (see Figure 1 below).

Lanthanum is assigned separately in group IIIa under Al, Sc, Y, while the remaining elements, Ce to Lu, labeled “Rare earths (Lanthanons)”, are grouped together but still placed in the IIIa box next to La. In the 25 years that passed between editions, the La–Lu problem was no closer to solution. Another 55 years have now gone by and the debate rages on: plus ça change, plus c’est la même chose.

The 1954 table in Figure 1 is interesting for two additional reasons. First, it shows hydrogen standing alone, remote from both Li and F, well removed from C, and above He and the inert gases. If ever there were an element that could be described as sui generis, hydrogen is it. Second, the table in Figure 1 also emphasizes the problem of where to locate the elements post Z = 89. The chemical properties of thorium and uranium are clearly quite different from what is expected from well-behaved lanthanide-like elements with their dominant, robust +3 oxidation states. The actinide hypothesis seems to take effect only from Z =  95 and onwards.

Arguing about the “right place” for thorium and uranium (or La and Lu or Ac and Lr) in a f- or d-series seems purposeless. Why “should” thorium, [Rn]6d27s2, be best placed in the f-block? It depends on your criteria.

Jensen is correct when he speaks of “alternative representations” and of the danger of insisting on one, and only one, officially endorsed form of the periodic table. John W. Moore made the point in 2003 (3) and so has Ronald L. Rich more recently (4); there is no ideal or perfect periodic table. Choose a table whose format best suits your needs. It is valuable that the students should see and understand and use the different arrangements.

Figure 1

Figure 1. The periodic classification from page 28 of ref 2. Note the positions of La (Z = 57) and elements Z = 58 to 71 in the same box; that hydrogen is divorced from the rest of the elements in the table; and the ambiguous positions of the “Actinons”.

Literature Cited

  1. Jensen, W. B. J. Chem. Educ. 2008, 85, 1491–1493.
  2. Ephraim, F. Inorganic Chemistry, 6th ed.; Oliver and Boyd: London, 1954; pp 28, 31; revised by P. C. L. Thorne and E. R. Roberts.
  3. Moore, J. W. J. Chem. Educ. 2003, 80, 847.
  4. Rich, R. L. J. Chem. Educ. 2005, 82, 1761–1763.
More Information
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Citation
Laing, Michael. J. Chem. Educ. 2009, 86, 1189.
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Keywords
First-Year Undergraduate / General; History / Philosophy; Inorganic Chemistry; Periodicity / Periodic Table; Physical Chemistry
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History
Created:
Last Updated:
8/25/2009
9/7/2009
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