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  Home > JCE Print > Journal of Chemical Education > Issues > 1999  > September  >
In the Classroom
Tested Demonstrations
A Classroom Demonstration of Rayleigh Light Scattering in Optically Active and Inactive Systems
submitted by: Monica Avalos Pecina and Charles A. Smith
Chemistry Department, Our Lady of the Lake University, 411 SW 24th Street, San Antonio, TX 78207-4689

checked by: Kristin Johnson
Department of Chemistry, University of Wisconsin, Madison, WI 53706

checked by: Penny Snetsinger
Department of Chemistry and Physics, Sacred Heart University, Fairfield, CT 06432

Cover
September 1999
Vol. 76 No. 9
p. 1230

Abstract
The objective of this demonstration is to allow students to make a direct observation of the rotation of polarized light in an optically active medium. The observation is performed by passing a laser beam through a long vertical cylinder, which contains a solution of a nonabsorbing optically active compound. Rayleigh scattered light from particulates in the solution allows a spiral pattern of light and dark areas to be observed. Students observe the three-dimensional nature of the spiral pattern by walking around the setup and viewing the cylinder and its contents on all sides. They can manipulate the spiral pattern by rotating the laser. To promote student understanding of the demonstration, a second demonstration is performed by replacing the optically active solution in the vertical cylinder with an optically inactive solution. The optically inactive demonstration allows students to observe scattered light that follows the theoretical directional radiation pattern of an oscillating dipole. Such Rayleigh scattering cross-sections are commonly encountered in discussions of Rayleigh scattering in many physical chemistry and modern optics textbooks. The demonstrations in this article are inexpensive and allow students to directly observe the results of Rayleigh scattering, optical activity, and the directional radiation pattern of an oscillating dipole.
More Information
*  Citation
Pecina, Monica Avalos; Smith, Charles A. J. Chem. Educ. 1999 76 1230.
*  Keywords
Demonstrations; Physical Chemistry; Organic Chemistry; Lasers / Laser Spectroscopy; Quantum Chemistry; Teaching / Learning Aids
*  History
Created:
Last Updated:
July 30, 1999
June 23, 2005
  Home > JCE Print > Journal of Chemical Education > Issues > 1999 > September > Page 1230


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